PrepYodhaClass Notes · Chemistry
Chemistry · Chapter 02

Atomic Structure

The atom is the basic building block of all matter, but it is itself made of still smaller charged particles arranged in a definite way. These notes move from the atom and its three sub-atomic particles, through the historical atomic models, to atomic number and mass number, isotopes and their cousins, and finally the way electrons fill up shells to decide an element's valency.

⚛️ 14 topics🎯 104+ points📝 self-test
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Topic 01

The Atom

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The atom is the smallest unit of an element that takes part in a chemical reaction, yet it can be broken further into smaller charged particles.

⭐
Key Point
The atom is the smallest particle of an element that can take part in a chemical reaction.
Key ideas about the atom
  • The word atom comes from the Greek *atomos*, meaning "indivisible" or that which cannot be cut.
  • John Dalton (1808) first used the term "atom" in modern science.
  • An atom is made of three sub-atomic particles — electron, proton and neutron.
  • The atom as a whole is electrically neutral because the number of protons equals the number of electrons.
  • An atom is extremely small; its radius is of the order of 10⁻¹⁰ metre (1 angstrom, Å).
📝 Quick self-test 2 MCQs · 2 fill-ups

The word 'atom' comes from the Greek 'atomos', meaning:

  1. Smallest
  2. Indivisible
  3. Charged
  4. Nucleus
✔ B. Indivisible — Atomos means indivisible, that which cannot be cut.

Who first used the term 'atom' in modern science?

  1. Rutherford
  2. Bohr
  3. John Dalton
  4. Thomson
✔ C. John Dalton — John Dalton (1808) first used the term atom in modern science.

An atom as a whole is electrically because protons equal electrons.

✔ neutral

The radius of an atom is of the order of 10⁻¹⁰ metre, i.e. one .

✔ angstrom
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Topic 02

Sub-atomic Particles

An atom is built from three fundamental particles — a negatively charged electron, a positively charged proton, and a neutral neutron.

⭐
Key Point
The electron carries a negative charge -1 and was discovered by J.J. Thomson (1897).
The three sub-atomic particles
  • The proton carries a positive charge +1 and was discovered by Goldstein (named by Rutherford).
  • The neutron carries no charge (0) and was discovered by James Chadwick (1932).
  • Protons and neutrons together make up the nucleus and are called nucleons.
  • Electrons revolve around the nucleus in fixed orbits or shells.
Sub-atomic particles — charge, mass & discoverer
ParticleSymbolChargeRelative massDiscoverer
Electrone⁻-11/1837 (≈ negligible)J.J. Thomson
Protonp⁺+11 (1.6726 × 10⁻²⁷ kg)Goldstein / Rutherford
Neutronn⁰01 (1.6749 × 10⁻²⁷ kg)James Chadwick
📝 Quick self-test 2 MCQs · 2 fill-ups

Which sub-atomic particle carries no charge?

  1. Electron
  2. Proton
  3. Neutron
  4. Ion
✔ C. Neutron — The neutron carries no charge (0).

Protons and neutrons together are called:

  1. Nucleons
  2. Electrons
  3. Isotopes
  4. Cations
✔ A. Nucleons — Protons and neutrons together make up the nucleus and are called nucleons.

The electron was discovered by .

✔ J.J. Thomson

The neutron was discovered by James .

✔ Chadwick
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Topic 03

The Electron

The electron is the lightest of the three particles and carries the unit negative charge.

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Key Point
Discovered by J.J. Thomson in 1897 through his cathode-ray (discharge tube) experiments.
Facts about the electron
  • Charge on an electron = -1.6 × 10⁻¹⁹ coulomb (the unit negative charge).
  • Mass of an electron = 9.1 × 10⁻³¹ kg, about 1/1837 of the mass of a proton — almost negligible.
  • Electrons are found outside the nucleus, revolving in shells.
  • The number of electrons decides the chemical properties of an atom.
📝 Quick self-test 2 MCQs · 2 fill-ups

The mass of an electron is about what fraction of a proton's mass?

  1. 1/1837
  2. 1/100
  3. 1
  4. 1/10
✔ A. 1/1837 — An electron's mass is about 1/1837 of a proton's — almost negligible.

Electrons are found:

  1. Inside the nucleus
  2. Outside the nucleus, revolving in shells
  3. In the neutron
  4. Fixed at the centre
✔ B. Outside the nucleus, revolving in shells — Electrons are found outside the nucleus, revolving in shells.

The charge on an electron is -1.6 × 10⁻¹⁹ .

✔ coulomb

The electron was discovered through his -ray (discharge tube) experiments.

✔ cathode
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Topic 04

The Proton

The proton carries the unit positive charge and sits inside the nucleus.

⭐
Key Point
Discovered by Goldstein (in his canal-ray / anode-ray experiment); the name "proton" was given by Rutherford.
Facts about the proton
  • Charge on a proton = +1.6 × 10⁻¹⁹ coulomb (the unit positive charge).
  • Mass of a proton = 1.6726 × 10⁻²⁷ kg, taken as relative mass 1.
  • The number of protons = atomic number (Z), which fixes the identity of the element.
  • Protons are present inside the nucleus.
📝 Quick self-test 2 MCQs · 2 fill-ups

The number of protons in an atom equals its:

  1. Mass number
  2. Atomic number
  3. Neutron number
  4. Valency
✔ B. Atomic number — The number of protons = atomic number (Z), which fixes the element's identity.

Who gave the name 'proton'?

  1. Goldstein
  2. Chadwick
  3. Rutherford
  4. Thomson
✔ C. Rutherford — Goldstein discovered it but the name proton was given by Rutherford.

The proton was discovered by in his canal-ray experiment.

✔ Goldstein

The charge on a proton is +1.6 × 10⁻¹⁹ .

✔ coulomb
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Topic 05

The Neutron

The neutron is electrically neutral and was the last of the three particles to be discovered.

⭐
Key Point
Discovered by James Chadwick in 1932.
Facts about the neutron
  • The neutron carries no charge (charge = 0) — it is electrically neutral.
  • Mass of a neutron = 1.6749 × 10⁻²⁷ kg, slightly more than a proton, taken as relative mass 1.
  • Neutrons are present inside the nucleus along with protons.
  • The neutron is the heaviest of the three sub-atomic particles.
  • Hydrogen (₁H¹) is the only atom that has no neutron.
📝 Quick self-test 2 MCQs · 2 fill-ups

Which is the only atom that has no neutron?

  1. Helium
  2. Hydrogen (₁H¹)
  3. Carbon
  4. Sodium
✔ B. Hydrogen (₁H¹) — Hydrogen (₁H¹) is the only atom that has no neutron.

The neutron is:

  1. The lightest sub-atomic particle
  2. The heaviest of the three sub-atomic particles
  3. Positively charged
  4. Found outside the nucleus
✔ B. The heaviest of the three sub-atomic particles — The neutron is the heaviest of the three sub-atomic particles.

The neutron carries a charge of .

✔ 0

Neutrons are present inside the along with protons.

✔ nucleus
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Topic 06

Dalton's Atomic Theory

John Dalton gave the first scientific theory of the atom, treating it as a tiny, solid, indivisible ball.

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Key Point
All matter is made of tiny indivisible particles called atoms.
Dalton's atomic theory (1808)
  • Atoms can neither be created nor destroyed in a chemical reaction.
  • Atoms of the same element are identical in mass and properties.
  • Atoms of different elements are different in mass and properties.
  • Atoms combine in small whole-number ratios to form compounds.
  • Drawback: it wrongly held the atom to be indivisible — later disproved by the discovery of electrons, protons and neutrons.
📝 Quick self-test 2 MCQs · 2 fill-ups

According to Dalton's theory, atoms in a chemical reaction:

  1. Can be created
  2. Can be destroyed
  3. Can neither be created nor destroyed
  4. Change into energy
✔ C. Can neither be created nor destroyed — Dalton held that atoms can neither be created nor destroyed in a chemical reaction.

The main drawback of Dalton's theory was that it held the atom to be:

  1. Neutral
  2. Indivisible
  3. Charged
  4. Spherical
✔ B. Indivisible — Dalton wrongly held the atom to be indivisible, later disproved by discovery of sub-atomic particles.

According to Dalton, atoms combine in small -number ratios to form compounds.

✔ whole

Dalton's atomic theory was proposed in the year .

✔ 1808
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Topic 07

Thomson's Model (Plum-Pudding Model)

After discovering the electron, J.J. Thomson pictured the atom as a positive sphere with electrons stuck in it.

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Key Point
The atom is a sphere of positive charge with electrons embedded in it, like seeds in a watermelon or plums in a pudding.
Thomson's plum-pudding model (1904)
  • Also called the plum-pudding, watermelon, or raisin-pudding model.
  • The positive and negative charges are equal, so the atom as a whole is neutral.
  • Drawback: it could not explain the nucleus or the results of Rutherford's experiment.
📝 Quick self-test 2 MCQs · 2 fill-ups

Thomson's model of the atom is popularly called the:

  1. Nuclear model
  2. Plum-pudding model
  3. Bohr model
  4. Solar-system model
✔ B. Plum-pudding model — Thomson's model is called the plum-pudding (watermelon) model.

In Thomson's model, the atom is a sphere of:

  1. Negative charge with protons in it
  2. Positive charge with electrons embedded in it
  3. Neutrons only
  4. Empty space
✔ B. Positive charge with electrons embedded in it — Thomson pictured a sphere of positive charge with electrons embedded in it.

A drawback of Thomson's model was that it could not explain the .

✔ nucleus

In Thomson's model the positive and negative charges are , so the atom is neutral.

✔ equal
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Topic 08

Rutherford's Nuclear Model (Gold-Foil Experiment)

Rutherford fired alpha particles at a thin gold foil and from the way they scattered concluded that the atom is mostly empty space with a tiny dense nucleus.

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Key Point
Most α-particles passed straight through the gold foil — so the atom is mostly empty space.
Rutherford's α-particle scattering (gold-foil) experiment (1911)
  • A few α-particles were deflected and very few bounced straight back — so there is a tiny, dense, positively charged centre.
  • This dense positive centre is the nucleus, where nearly all the mass is concentrated.
  • Electrons revolve around the nucleus like planets around the Sun.
  • The nucleus is very small compared to the atom (radius ~10⁻¹⁵ m vs atom ~10⁻¹⁰ m).
  • Drawback: by classical physics a revolving electron should lose energy and spiral into the nucleus, making the atom unstable — which it does not.
📝 Quick self-test 2 MCQs · 2 fill-ups

Rutherford's gold-foil experiment showed that the atom is:

  1. Solid throughout
  2. Mostly empty space
  3. Made only of electrons
  4. A uniform sphere of charge
✔ B. Mostly empty space — Most α-particles passed straight through, showing the atom is mostly empty space.

The tiny, dense, positively charged centre of the atom is the:

  1. Shell
  2. Electron cloud
  3. Nucleus
  4. Orbit
✔ C. Nucleus — Rutherford concluded the dense positive centre is the nucleus.

Rutherford fired particles at a thin gold foil.

✔ alpha (α)

A drawback was that a revolving electron should lose energy and into the nucleus.

✔ spiral
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Topic 09

Bohr's Model

Niels Bohr fixed the flaw in Rutherford's model by allowing electrons only in certain fixed, stable orbits.

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Key Point
Electrons revolve only in certain fixed circular paths called orbits, shells or energy levels.
Bohr's model of the atom (1913)
  • These shells are named K, L, M, N… (or numbered n = 1, 2, 3, 4…).
  • While in a fixed orbit, an electron does not lose energy — the orbit is a stable, stationary state.
  • Energy is absorbed when an electron jumps to a higher shell and emitted (released) when it falls to a lower shell.
  • This explained the stability of the atom that Rutherford's model could not.
📝 Quick self-test 2 MCQs · 2 fill-ups

In Bohr's model, electrons revolve only in:

  1. Random paths
  2. Fixed circular orbits or shells
  3. The nucleus
  4. Straight lines
✔ B. Fixed circular orbits or shells — Bohr allowed electrons only in certain fixed circular paths called orbits or shells.

According to Bohr, energy is absorbed when an electron:

  1. Jumps to a higher shell
  2. Falls to a lower shell
  3. Stays in its orbit
  4. Leaves the atom
✔ A. Jumps to a higher shell — Energy is absorbed when an electron jumps to a higher shell and released when it falls.

Bohr's shells are named K, L, M, from the nucleus outward.

✔ N

Bohr's model explained the of the atom that Rutherford's could not.

✔ stability
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Topic 10

Atomic Number & Mass Number

Two numbers fix the make-up of an atom's nucleus — the atomic number counts the protons, the mass number counts protons plus neutrons.

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Key Point
Atomic number Z = number of protons in the nucleus.
Atomic number and mass number
  • In a neutral atom, number of protons = number of electrons, so Z also equals the number of electrons.
  • Mass number A = number of protons + number of neutrons (A = Z + N).
  • Number of neutrons N = A − Z (mass number minus atomic number).
  • An element is written as ₓXᴬ or ᴬ_ZX, where X = symbol, Z = atomic number, A = mass number.
  • Example: Sodium ₁₁Na²³ has Z = 11 (11 protons, 11 electrons) and A = 23, so N = 23 − 11 = 12 neutrons.
📝 Quick self-test 2 MCQs · 2 fill-ups

The mass number (A) of an atom equals:

  1. Protons only
  2. Protons + neutrons
  3. Neutrons only
  4. Electrons + protons
✔ B. Protons + neutrons — Mass number A = number of protons + number of neutrons.

For sodium ₁₁Na²³, the number of neutrons is:

  1. 11
  2. 23
  3. 12
  4. 34
✔ C. 12 — N = A − Z = 23 − 11 = 12 neutrons.

The number of neutrons N = A − .

✔ Z

In a neutral atom the number of protons equals the number of .

✔ electrons
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Topic 11

Isotopes, Isobars & Isotones

Atoms can match each other in protons, in mass number, or in neutrons — giving three different "iso-" families.

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Key Point
Isotopes — same atomic number Z (same protons), different mass number A (different neutrons).
The three families
  • Isobars — same mass number A, but different atomic number Z (different elements).
  • Isotones — same number of neutrons N, but different Z and A.
Isotopes vs Isobars vs Isotones
TypeWhat is sameWhat differsExample
IsotopesAtomic number Z (protons)Mass number A (neutrons)₁H¹, ₁H², ₁H³ (Protium, Deuterium, Tritium); ₆C¹², ₆C¹⁴
IsobarsMass number AAtomic number Z₁₈Ar⁴⁰ and ₂₀Ca⁴⁰
IsotonesNumber of neutrons NZ and A₆C¹⁴ and ₈O¹⁶ (each has 8 neutrons)
Extra isotope facts
  • Hydrogen has three isotopes: Protium (₁H¹), Deuterium (₁H²) and Tritium (₁H³).
  • Isotopes have the same chemical properties (same electrons) but different physical properties (different mass).
  • Carbon-14 (₆C¹⁴) is a radioactive isotope used in carbon dating; Cobalt-60 is used in cancer treatment.
📝 Quick self-test 2 MCQs · 2 fill-ups

Atoms with the same atomic number but different mass numbers are called:

  1. Isobars
  2. Isotones
  3. Isotopes
  4. Ions
✔ C. Isotopes — Isotopes have the same atomic number Z but different mass number A.

₁₈Ar⁴⁰ and ₂₀Ca⁴⁰ are examples of:

  1. Isotopes
  2. Isobars
  3. Isotones
  4. Allotropes
✔ B. Isobars — They have the same mass number 40 but different atomic numbers, so they are isobars.

Isotones have the same number of but different Z and A.

✔ neutrons

Carbon-14 (₆C¹⁴) is a radioactive isotope used in carbon .

✔ dating
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Topic 12

Electronic Configuration & Shells

Electrons are arranged in shells around the nucleus, and each shell can hold only a fixed maximum number of electrons.

⭐
Key Point
Electrons are arranged in shells named K, L, M, N… from the nucleus outward.
Filling of shells
  • The maximum number of electrons in a shell = 2n², where n is the shell number.
  • The shell nearest the nucleus (K) has the lowest energy and fills first.
  • The outermost shell can hold a maximum of 8 electrons (the octet rule, for stability).
Shell ↔ maximum electrons (2n²)
ShellnMaximum electrons (2n²)
K12 × 1² = 2
L22 × 2² = 8
M32 × 3² = 18
N42 × 4² = 32
  • Example: Sodium (Z = 11) → 2, 8, 1 (K = 2, L = 8, M = 1).
📝 Quick self-test 2 MCQs · 2 fill-ups

The maximum number of electrons in a shell is given by:

  1. 2n
  2. n²
  3. 2n²
  4. 8
✔ C. 2n² — The maximum electrons in a shell = 2n², where n is the shell number.

The maximum number of electrons the M shell can hold is:

  1. 2
  2. 8
  3. 18
  4. 32
✔ C. 18 — For the M shell n = 3, so 2 × 3² = 18 electrons.

The outermost shell can hold a maximum of electrons.

✔ 8

The electronic configuration of sodium (Z = 11) is 2, 8, .

✔ 1
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Topic 13

Valence Shell, Valence Electrons & Valency

The outermost shell decides how an atom bonds, through the number of electrons it has and how many it needs to become stable.

⭐
Key Point
The outermost shell of an atom is called the valence shell.
Valence shell and valence electrons
  • The electrons in the valence (outermost) shell are called valence electrons.
  • Valence electrons decide the chemical (bonding) behaviour of an atom.
Valency
  • Valency is the combining capacity of an atom — the number of electrons it gains, loses or shares to become stable.
  • An atom is most stable with 8 electrons in its outer shell (octet); helium is stable with 2 (duplet).
  • If valence electrons ≤ 4, valency = number of valence electrons; if > 4, valency = 8 − valence electrons.
  • Example: Sodium (2, 8, 1) has 1 valence electron, so valency = 1.
  • Example: Chlorine (2, 8, 7) has 7 valence electrons, so valency = 8 − 7 = 1.
  • Noble gases have a complete outer shell, so their valency is 0 (inert/unreactive).
📝 Quick self-test 2 MCQs · 2 fill-ups

The electrons in the outermost shell of an atom are called:

  1. Core electrons
  2. Valence electrons
  3. Free electrons
  4. Nucleons
✔ B. Valence electrons — The electrons in the valence (outermost) shell are called valence electrons.

The valency of chlorine (2, 8, 7) is:

  1. 7
  2. 1
  3. 8
  4. 2
✔ B. 1 — With 7 valence electrons, valency = 8 − 7 = 1.

Valency is the capacity of an atom.

✔ combining

Noble gases have a complete outer shell, so their valency is .

✔ 0
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Topic 14

Why Atoms Are Electrically Neutral

Although an atom contains charged particles, it shows no overall charge because the positive and negative charges exactly cancel.

⭐
Key Point
An atom has equal numbers of protons (+) and electrons (−).
Reason for electrical neutrality
  • The total positive charge equals the total negative charge, so the net charge is zero.
  • The neutron has no charge, so it does not affect the balance.
  • When an atom loses or gains electrons it becomes a charged ion: losing electrons gives a positive cation, gaining electrons gives a negative anion.
📝 Quick self-test 2 MCQs · 2 fill-ups

An atom is electrically neutral because:

  1. It has no neutrons
  2. Protons equal electrons in number
  3. It has only protons
  4. Electrons carry no charge
✔ B. Protons equal electrons in number — An atom has equal numbers of protons (+) and electrons (−), so the net charge is zero.

An atom that loses electrons becomes a:

  1. Neutron
  2. Positive cation
  3. Negative anion
  4. Nucleon
✔ B. Positive cation — Losing electrons gives a positive ion called a cation.

The has no charge, so it does not affect the charge balance of the atom.

✔ neutron

An atom that gains electrons becomes a negative ion called a/an .

✔ anion
🎯
Recap

Quick Revision

⭐
Key Point
The atom is the smallest particle of an element that takes part in a chemical reaction; *atomos* means "indivisible".
  • Electron: charge -1, J.J. Thomson; Proton: charge +1, Goldstein/Rutherford; Neutron: charge 0, Chadwick.
  • Electron mass ≈ 1/1837 of a proton (negligible); proton and neutron each have relative mass 1 and form the nucleus.
  • Hydrogen (₁H¹) is the only atom with no neutron.
  • Dalton — indivisible atom; Thomson — plum-pudding model; Rutherford — nuclear model (gold-foil); Bohr — fixed orbits/shells.
  • Rutherford's gold-foil experiment showed the atom is mostly empty space with a tiny dense nucleus.
  • Atomic number Z = number of protons (= electrons in a neutral atom); mass number A = Z + N; neutrons N = A − Z.
  • Isotopes — same Z, different A; Isobars — same A, different Z; Isotones — same number of neutrons.
  • Hydrogen's isotopes: Protium, Deuterium, Tritium; C-14 is used in carbon dating.
  • Shells K, L, M, N hold a maximum of 2n² electrons (2, 8, 18, 32); outermost shell holds at most 8.
  • Valence electrons = electrons in the outermost (valence) shell; valency = combining capacity of the atom.
  • Noble gases have valency 0 (complete outer shell, inert).
  • An atom is electrically neutral because protons (+) = electrons (−); losing/gaining electrons forms ions (cation +, anion −).

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